I tested it a bit in a VM to get familiar with pacman and yay. Latest KDE Plasma 6 and more snaps in Ubuntu's future are the main reasons I want to switch.
As I don't use a separate home partition, I have an extra drive with BackInTime home dir backups and virtnbdbackup snapshots.
Is EndeavourOS stable enough for everyday use and would restoring home with BackInTime just work (as root user)?
Not specific advice, but make sure all the programs you use are available and where/how you will get them.
The AUR is the second-biggest software repository in the world