I've dabbled with Linux over the years, first with Ubuntu in the early 2010s, then Elementary OS when that dropped, and a few years ago I really enjoyed how customizable the gui was with Xubuntu. I was able to make it look just like WIndows 2000 which was really cool.
Which current distro has the best GUI, in your opinion? I find modern Ubuntu to feel a little basic and cheap. I guess I don't really like modern Gnome. I'm currently using Windows 10 LTSC which is probably the best possible version of Windows, but I'd jump to linux if I could find a distro with a gui that feels at least as polished and feature rich as Windows 10 LTSC.
Distro is irrelevant. DE/WM choice is all that matters as far as GUI goes. Also, if you want a GUI that looks or feels like windows then KDE probably has you covered in that you could probably customise it to mimic windows.
I quite like the Desktop Environment in elementaryOS. I think it's called Pantheon Desktop? It's very polished. Or InstantWM from InstantOS is also interesting and has some nice animations and effects.
Personally, I use simple and minimal Openbox